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Can you get a spotter? Maybe some stuff to failure would work for you.
What's your real goal, though? To get a bigger chest, or lift more weight?
Bigger muscles, you could try super-slow sets. There's a Cambodian guy in my gym, he lifts about half the weight I do, but it's slow, careful and with absolutely perfect form - and his muscles are bigger than mine.
More weight, have a chat to a powerlifter. Those guys have all sorts of funky techniques with arching their back and flinging their legs around to get weight up there. Couldn't really describe it easily in words, and anyway I've never done it myself.
How about trying to break through your 100kg and go for 110kg or even 120kg instead.
You may only get 2 or 3 reps in (after a good warm up), but you can work on increasing them over time.
Then you could go back to 100kg if you want, and do it easy.
I did this when I weas younger, lifted my 1 or 2 rep max, and used the same weight over time to build up the reps to 6 or 8, then smash the weight up another level and do it all again.
I think this is called the double progression method.
if your goal is definition why do you want to do 10reps at 100kg?
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